Comparative study for removal of cationic and anionic dyes using alginate-based hydrogels filled with citric acid-sawdust/UiO-66-NH2 hybrid.

Nowadays, a big challenge is developing a sustainable and effective method for removing contaminants like dyes from aqueous solutions. In this regard, Zr-based metal-organic framework (UiO-66-NH2) and sawdust as the ideal adsorbents were used. Due to their low separation in adsorption processes, embedding into alginate and obtaining composite beads are suggested as a suitable strategy. The achieved Ca-alginate/citric acid (CA)-sawdust/UiO-66-NH2 hydrogel beads were used to compare cationic and anionic dyes removal. This sorbent indicated an excellent selectivity for removing methylene blue versus methyl orange in a binary system. pH = 6, adsorbent amount = 80 mg, methylene blue concentration = 10 mg/L, and contact time = 420 min were achieved as optimal parameters on methylene blue adsorption with an adsorption capacity of about 26 mg/g. The removal process of methylene blue followed linear Freundlich isotherm and nonlinear pseudo-2nd-order kinetic models. The regeneration test demonstrated methylene blue removal efficiency higher than about 89 % after 9 cycles. According to the outcomes, methylene blue could be attached to the adsorbent surface through the electrostatic, hydrogen bonding, and π-π interactions of the aromatic rings. These results confirm the potential of Ca-alginate/CA-sawdust/UiO-66-NH2 hydrogel beads as a selective bio-sorbent for cationic dye removal.

Chitosan/tannic acid/ZnFe layered double hydroxides and mixed metal oxides nanocomposite for the adsorption of reactive dyes.

The fabrication of the environmentally friendly nanocomposite beads containing chitosan (Chi), tannic acid (TA), layered double hydroxides (LDH), and mixed metal oxides (MMO) was carried out. The synthesized ZnFe LDH, ZnFe MMO, and fabricated beads (Chi/TA@LDH and Chi/TA@MMO) were characterized using FESEM, XRD, FTIR, BET, and TGA. The beads were applied for the simultaneous removal of three reactive dyes. The design of experiments was based on a full factorial design considering the effect of six independent variables (initial dye concentrations, adsorbent dosage, time, and adsorbent type) on the dye removal percentages (DR%) of each dye. Regression equations were extracted from the experimental results (R2 > 0.983) and high obtained F-values from analysis of variance (ANOVA) proved the significance of the models. The maximum adsorption capacity of the dyes onto, Chi/TA@LDH and Chi/TA@MMO beads were between 257 and 483 mg g-1. The spontaneity and exothermic nature of the adsorption processes were determined by thermodynamic studies (-8 < ΔH° (KJ mol-1) < -1, -22 < ΔG° (KJ mol-1) < -18). Reusability studies showed that the fabricated beads could be regenerated and applied several times.

Removal of cationic and anionic dyes using Ca-alginate and Zn-Al layered double hydroxide/metal-organic framework.

In this study, a novel effective bio adsorbent was produced and employed to remove congo red and methylene blue dyes from water matrices. First, Zn-Al layered double hydroxide (Zn-Al LDH) was manufactured in a hydrothermal process. Next, through in-situ nucleation and growing of crystalline NH2-modified Ti metal-organic framework (NH2-MIL-125(Ti) on Zn-Al sheets by solvothermal method, Zn-Al LDH@NH2-MIL-125(Ti) hybrid was produced. The prepared hybrid showed good adsorption capacity (qmax values: 294 mg/g and 158 mg/g) for congo red and methylene blue dyes in optimum condition (adsorbent amount = 5-7 mg, dye concentration = 100-150 mg/L, V = 10 mL, pH = no adjustment, and contact time = 2-5 h). Based on the isotherm and kinetic models, the Langmuir isotherm, as well as the pseudo-second-order model, were fit to the equilibrium data. In the next attempt, to improve the reusability of the powder and particle form of Zn-Al LDH@NH2-MIL-125(Ti) hybrid, as well as prevent of formation of secondary contamination in water, Na-alginate, as a cheap and effective substrate, was used. Novel architectures of robust, reusable, and efficient Ca-alginate/Zn-Al LDH@NH2-MIL-125(Ti) microgel beads were prepared and the performances of the microbeads were compared with pure LDH@NH2-MIL-125(Ti) hybrid.

Worldwide fight against COVID-19 using nanotechnology, polymer science, and 3D printing technology.

One of the lethal illnesses that humanity has ever seen is COVID-19 irrefutably. The speed of virus spread is high and happens through polluted surfaces, respiratory droplets, and bodily fluids. It was found that without an efficient vaccine or specific treatment using personal protective equipment, preventing contamination of hands, and social distancing are the best ways to stay safe during the present pandemic. In this line, polymers, nanotechnology, and additive manufacturing, or 3D printing technology have been considered to probe, sense, and treat COVID-19. All aforementioned fields showed undeniable roles during the COVID-19 pandemic, which their contributions have been reviewed here. Finally, the effect of COVID-19 on the environment, alongside its positive and negative effects has been mentioned.

Bio-sorbent alginate/citric acid-sawdust/Fe3O4 nanocomposite beads for highly efficient removal of malachite green from water.

Sawdust is a by-product of wood-related industries with striking features for pollutant uptake. For the first time in the current study, sustainable magnetic alginate composite beads containing citric acid-modified sawdust (CA-sawdust) as a bio-waste and Fe3O4 nanoparticles were designed. This novel eco-friendly composite (Alginate/CA-sawdust/Fe3O4 beads) was successfully applied to remove cationic malachite green (MG). Easy separation under a magnetic field and reusability could be mentioned as two significant properties of this bio-sorbent. The removal percentage of MG using alginate/CA-sawdust/Fe3O4 beads was calculated to be 90-95 %. This process was well-described with Langmuir isotherm and nonlinear pseudo-first-order kinetic models. Moreover, both film and intraparticle diffusion models were found to be probable removal mechanisms.

Amino-functionalized cross-linked cellulosic fabric with antibacterial, UV protection, and coloring effects using folic acid.

The amino-functionalized cellulose with folic acid, via an esterification reaction between carboxylic acid of folic acid and hydroxyl groups of cellulose, can develop multifunctional products with new chemical and physical properties. Folic acid contains two carboxylic groups as well as an amine group that can be used as a coupling agent and provide suitable conditions for coupling hydroxyl-based compounds to cellulose. Also; the multi-functionalized cellulose with folic acid has no effects on the physical and mechanical properties and also has benefits such as antibacterial, UV protection, and wrinkle resistance. The FTIR-ATR and Raman analysis confirmed the amino functionalized-cellulosic fabric via an esterification reaction between cellulose and folic acid. The cell viability of L929 fibroblast (NCBI C161) and MCF-7 (NCBI C135) cancer cells indicated more effectiveness on MCF-7 cancer cells. Therefore; folic acid can be used as a biocompatible natural cross-linker to modify cellulose fabrics for apparel and medical applications.

Optimization of chitosan/tannic acid@ ZnFe layered double hydroxide bionanocomposite film for removal of reactive blue 4 using a response surface methodology.

Layered double hydroxides (LDH) are great adsorbents for anionic pollutants, but are in a powder form that leads to challenges in solid-liquid separation, low hydraulic conductivity, and handling. Herein, novel bionanocomposite films containing chitosan (Cs), tannic acid (TA), and LDH were fabricated and applied for the removal of reactive blue 4 (RB4). A response surface methodology with Box-Behnken design was applied to study the effect of operating parameters (TA%: 0-20, LDH%: 0-20, pH: 5-9, adsorbent dosage: 0.5-1.5 g L-1, time: 30-90 min) on RB4 dye removal (DR%). A quadratic regression equation was successfully developed to predict the response (R2: 0.95). The obtained optimized condition was TA%: 10, LDH%: 20, pH: 5, adsorbent dosage: 1.5 g L-1, and time: 71 min that resulted in DR%: 98.2. The best-fitted adsorption isotherm and kinetic models were linear Langmuir and nonlinear pseudo-second-order models, respectively. The maximum capacity of adsorption for the optimized film was 406 mg g-1. The obtained thermodynamic parameters implied that the process of adsorption was exothermic and spontaneous. The reusability studies showed that the DR% was decreased from 93% for the first cycle to 69%, 57%, and 56% for the second, third and fourth cycle, respectively.

Removal of the Anionic Dye Congo Red from an Aqueous Solution Using a Crosslinked Poly(vinyl alcohol)-ZnO-Vitamin M Nanocomposite Film: A Study of the Recent Concerns about Nonlinear and Linear Forms of Isotherms and Kinetics.

This paper deals with the preparation, characterization, and application of a crosslinked poly(vinyl alcohol)/ZnO-vitamin M (PVA/ZnO-VM) nanocomposite film for the removal of Congo red (CR) from an aqueous solution. The characterization of a crosslinked PVA/ZnO-VM nanocomposite film showed that the structure became more regular and also the surface morphology appeared smooth in comparison with pure PVA. The obtained data from Brunauer-Emmett-Teller (BET) proved the mesoporous structure for this nanocomposite film. Several effective factors were examined for the adsorption ability of the nanocomposite film, including solution pH (2-10), sorbent amount (0.02-0.08 g), contact time (3-240 min), initial concentration of the adsorbate (30-300 mg·L-1), and temperature (318-358 K). The optimal conditions are as follows: pH = 10, adsorbent amount = 0.06 g, and C0 = 200 mg·L-1. The removal efficiency of the nanocomposite film was 92% after 4 h at the ambient temperature. To interpret the adsorption process, nonlinear and linear forms of kinetic and isotherm models were considered. The obtained data followed nonlinear pseudo-second-order and linear Langmuir isotherm models, which indicated the monolayer formation of CR over the crosslinked PVA/ZnO-VM nanocomposite film with the maximum adsorption capacity of about 56.49 mg·g-1. Also, the adsorption process of CR by the crosslinked PVA/ZnO-VM nanocomposite film is a spontaneous and exothermic reaction.

Development of sodium alginate-pectin/TiO2 nanocomposites: Antibacterial and bioactivity investigations.

In this research, sodium alginate-pectin composite (ALG-PEC CS) and nanocomposites (NCs) films with 0.5, 1, and 2 wt% TiO2 nanoparticles (NPs) were prepared using CaCl2 and glutaraldehyde (Glu) as cross-linkers. The cross-linking produces rigid scaffolds for sedimentation of hydroxyapatite (HA), it can also decrease solubility in water and simulated body fluid (SBF) solution to 10% or less. The increase of the adsorbed water and SBF extends the pores and consequently the surface area for HA growth. Bioactive ability was confirmed via HA's presence on the all films. It was revealed that the film containing 2 wt% TiO2 NPs had the best bioactivity without any in vitro cytotoxicity on MG-63 cell line and the best antibacterial performance against Staphylococcus aureus, and after 1 h all the bacteria were killed.

Fabrication of air filters with advanced filtration performance for removal of viral aerosols and control the spread of COVID-19.

COVID-19 is caused via the SARS-CoV-2 virus, a lipid-based enveloped virus with spike-like projections. At present, the global epidemic of COVID-19 continues and waves of SARS-CoV-2, the mutant Delta and Omicron variant which are associated with enhanced transmissibility and evasion to vaccine-induced immunity have increased hospitalization and mortality, the biggest challenge we face is whether we will be able to overcome this virus? On the other side, warm seasons and heat have increased the need for proper ventilation systems to trap contaminants containing the virus. Besides, heat and sweating accelerate the growth of microorganisms. For example, medical staff that is in the front line use masks for a long time, and their facial sweat causes microbes to grow on the mask. Nowadays, efficient air filters with anti-viral and antimicrobial properties have received a lot of attention, and are used to make ventilation systems or medical masks. A wide range of materials plays an important role in the production of efficient air filters. For example, metals, metal oxides, or antimicrobial metal species that have anti-viral and antimicrobial properties, including Ag, ZnO, TiO2, CuO, and Cu played a role in this regard. Carbon nanomaterials such as carbon nanotubes, graphene, or derivatives have also shown their role well. In addition, natural materials such as biopolymers such as alginate, and herbal extracts are employed to prepare effective air filters. In this review, we summarized the utilization of diverse materials in the preparation of efficient air filters to apply in the preparation of medical masks and ventilation systems. In the first part, the employing metal and metal oxides is examined, and the second part summarizes the application of carbon materials for the fabrication of air filters. After examination of the performance of natural materials, challenges and progress visions are discussed.

A new trend of using poly(vinyl alcohol) in 3D and 4D printing technologies: Process and applications.

Recently, 3D/4D printing technologies have been the researchers' interest, and they are getting improved more important. They are applicable in various fields like medical fields, pharmaceutics, construction, tissue engineering, dentistry, water treatment, etc. These technologies overcame the difficulty of the conventional methods in producing complicated structures. They can be fed by different materials such as nanomaterials, smart polymers, responsive polymers, metamaterials, synthetic polymers, natural polymers, and so forth. One of the smart and stimuli-responsive polymers is poly(vinyl alcohol) (PVA). In addition to numerous applications of PVA like medicine, environmental fields, etc., researchers are showing a tendency to use PVA in 3D/4D printing technologies. The main reasons for PVA's increased interest in 3D/4D printing technologies are suitable flowability, stimuli-responsivity, extrudability, biocompatibility, biodegradability, cost-effectiveness, and other features. This review aims to introduce the 3D/4D printing technologies' knowledge and then the applications of PVA as a feed in these novel technologies.

Single-Atoms on Covalent or Metal-Organic Frameworks: Current Findings and Perspectives for Pollutants Abatement, Hydrogen Evolution, and Reduction of CO2.

Nowadays, attention to single-atoms and also porous structures like metal-organic frameworks (MOFs) and covalent-organic frameworks (COFs) for the preparation of high-performance material is expanding rapidly. These dazzling materials with unprecedented properties have lots of applications, especially as promising catalysts for organic pollutants abatement, hydrogen evolution, reduction of CO2, etc. To provide an in-depth understanding, in this mini-review, we begin with a brief description and a general background about single-atoms, COFs, as well as MOFs. After considering some fundamentals, the synergism effects, advantages, and their applications are discussed.

Recent advancements in synthesis and drug delivery utilization of polysaccharides-based nanocomposites: The important role of nanoparticles and layered double hydroxides.

Drug delivery systems are explained as methods to deliver a specific drug to desired organs, tissues, and cells for drug release to diseases treatment. Recently, considerable development has been interested in stimuli-responsive nano-systems, which respond to the essential pathological and physicochemical issues in diseased sites. During the last decades, researchers in the world presented, investigated, and implemented novel different nanomaterials with a focus on developing drug delivery. Polysaccharides including chitosan, alginate, hyaluronic acid, gums, and cellulose, as natural bio-materials, are suitable candidates for designing and formulations of these nano-systems because of the outstanding merits such as bio-compatibility, bio-degradability, non-toxicity, and gelling characteristics. On the other side, nanoparticles including metals (Au, Ag), metal oxides (Fe3O4, ZnO, CuO), or non-metal oxides (SiO2) and also, layered double hydroxides nanostructures have appealed significant consideration in the fields of biomedical therapeutics and cancer therapy owing to the bio-compatibility, great surface area, good chemical and mechanical features, and also proper magnetic characteristics. This comprehensive review provides an overview of current advancements in drug delivery strategies, and manufacturing methods using chitosan, alginate, hyaluronic acid, gums, and also, metals, metal oxides, non-metal oxides, and LDHs for delivery system uses.

Sawdust, a versatile, inexpensive, readily available bio-waste: From mother earth to valuable materials for sustainable remediation technologies.

Sawdust or wood shaving is a relatively abundant and inexpensive lignocellulosic compound, which is provided by mother nature. It is a waste of industry and agriculture, that is found in large quantities and has disposal problems. Nowadays, waste management (like sawdust) and research on converting it to different compounds for special applications and goals have been receiving tremendous attention. So, introducing sawdust as a kind of interesting bio-waste and turn it into wealth for diverse utilizations can be mentioned as the main goal of this overview. In this regard, in the first part, sawdust structure and properties are considered. It is then followed by highlighting its wide applications in sustainable water remediation technology, production of activated carbon, oil-water separation, and high-performance composites fabrication. Please come on to start a journey on this motivating topic.

3D and 4D printing: From innovation to evolution.

The world and science are moving forward nonstop. Every day, we see novel technologies that are coming to improve life quality. One of them is 3D printing or additive manufacturing. This technology covers the shortage of the current manufacturing technologies, and it has been enhanced by introducing smart materials like smart polymers as feed. The following product can adapt to circumstance conditions such as temperature changes, compression alteration, etc. These responses resulted in an advanced 3D printing technology called 4D printing. 3D and 4D printing technologies found their applications in all areas and industry sizes, from home-scale to large-scale industries. Regardless of all advantages of these technologies, there are still some shortages like low printing speed. But this never stops their progression and promotion. In this review, we aimed to cover general knowledge about 3D and 4D printing and their recent applications in various fields.

Effective adsorption of methylene blue dye from water solution using renewable natural hydrogel bionanocomposite based on tragacanth gum: Linear-nonlinear calculations.

Today, hydrogels opened new windows to the high-tech due to their amazing features. Thus, we applied hydrogel nanocomposite (HNC) made of tragacanth gum (a kind of polysaccharide) and CaCO3 nanoparticles to remove methylene blue dye (MBD) from the water solution. We used nonlinear and linear isotherms and kinetics as well as thermodynamics to uncover the adsorption mechanism. The results showed that the hydrogel could remove 80% of MBD. Besides, the linear form of the pseudo-second-order kinetic model fits well with the results, showing chemical interactions. We found that this process follows both Sips and Redlich-Peterson models by applying nonlinear and linear isotherm models. The maximum adsorption capacities from nonlinear and linear Sips were 1401 and 2145 mg/g, respectively. Based on the thermodynamic equations, the adsorption of MBD onto HNC was physiochemical and exothermic. According to the phenomenological calculations, diffusion from the bulk (or film diffusion, Df = 1.2 × 10-8 cm2/s) is the primary mechanism.

Recent breakthroughs of antibacterial and antiviral protective polymeric materials during COVID-19 pandemic and after pandemic: Coating, packaging, and textile applications.

The global epidemic owing to COVID-19 has generated awareness to ensuring best practices for avoiding the microorganism spread. Indeed, because of the increase in infections caused by bacteria and viruses such as SARS-CoV-2, the global demand for antimicrobial materials is growing. New technologies by using polymeric systems are of great interest. Virus transmission by contaminated surfaces leads to the spread of infectious diseases, so antimicrobial coatings are significant in this regard. Moreover, antimicrobial food packaging is beneficial to prevent the spread of microorganisms during food processing and transportation. Furthermore, antimicrobial textiles show an effective role. We aim to provide a review of prepared antimicrobial polymeric materials for use in coating, food packaging, and textile during the COVID-19 pandemic and after pandemic.

Tragacanth gum mediated green fabrication of mesoporous titania nanomaterials: Application in photocatalytic degradation of crystal violet.

Water remediation is a crucial subject in present century. Hence, several processes have been used for this aim, which the photodegradation method with high activity, cost-effectiveness, and durability has been remarkable. In this project, the various novel mesoporous Titania nanomaterials (MTN) were green synthesized using Tragacanth gum as coupling agent. The effect of calcination times on the crystalline structure of the resulted MTNs was examined. MTNs displayed the dramatically specific surface area with negative surface charge and nano-sheet structure, and they applied for photodegradation of crystal violet under ultraviolet irradiation due to proper band gaps energy. The obtained MTN in 8 h calcination time (MTN-8) showed the best photoreduction activity. Also, the superoxide radicals, electrons, and hole pairs represented the main degradation agents as the reduction rate of crystal violet. Next, the transformation pathways were proposed, which could be transformation singlet oxygen addition, hydroxyl addition, and N-demethylation reactions.

Chitosan, alginate, hyaluronic acid, gums, and ß-glucan as potent adjuvants and vaccine delivery systems for viral threats including SARS-CoV-2: A review.

Pathogen transmission is a widespread threat to global human health. Vaccines are very important during the outbreak of a pandemic. Destructive fractures caused by a sudden outbreak of COVID-19 have spurred vaccine production at an unprecedented rate. The strategy of an effective vaccine delivery system is opening up novel probabilities to make more immunization. Indeed, vaccination is the most successful way to prevent deaths from infectious diseases. In order to optimal immune response production or improvement in the effectiveness of vaccines, delivery systems or adjuvants are required. Natural polymers such as chitosan, alginate, hyaluronic acid, gums, and ß-glucan with antiviral activity have good potential as adjuvant or delivery systems for vaccine formulation development and design vaccine delivery devices. According to the antiviral performance and immunomodulation of these biopolymers, they will play significant characters in the anti-COVID-19 field. In this mini-review, the recent progress in vaccine development by using biopolymers is presented which, provides a reference for their research on anti-COVID-19 drugs and vaccines.

State-of-the-art of 3D printing technology of alginate-based hydrogels-An emerging technique for industrial applications.

Recently, three-dimensional (3D) printing (also known as additive manufacturing) has received unprecedented consideration in various fields owing to many advantages compared to conventional manufacturing equipment such as reduced fabrication time, one-step production, and the ability for rapid prototyping. This promising technology, as the next manufacturing revolution and universal industrial method, allows the user to fabricate desired 3D objects using a layer-by-layer deposition of material and a 3D printer. Alginate, a versatile polysaccharide derived from seaweed, is popularly used for this advanced bio-fabrication technique due to its printability, biodegradability, biocompatibility, excellent availability, low degree of toxicity, being a relatively inexpensive, rapid gelation in the presence of Ca2+ divalent, and having fascinating chemical structure. In recent years, 3D printed alginate-based hydrogels have been prepared and used in various fields including tissue engineering, water treatment, food, electronics, and so forth. Due to the prominent role of 3D printed alginate-based materials in diverse fields. So, this review will focus and highlight the latest and most up-to-date achievements in the field of 3D printed alginate-based materials in biomedical, food, water treatment, and electronics.